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Ionized manganese is used industrially as pigments of various colors, which depend on the oxidation state of the ions.

The permanganates of alkali and alkaline earth metals are powerful oxidizers.

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While the element is a required trace mineral for all known living organisms, it also acts as a neurotoxin in larger amounts.

Especially through inhalation, it can cause manganism, a condition in mammals leading to neurological damage that is sometimes irreversible. All of the remaining radioactive isotopes have half-lives of less than three hours, and the majority of less than one minute.

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By the mid-18th century, Swedish-German chemist Carl Wilhelm Scheele had used pyrolusite to produce chlorine.

Scheele and others were aware that pyrolusite (now known to be manganese dioxide) contained a new element, but they were unable to isolate it.

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Johan Gottlieb Gahn was the first to isolate an impure sample of manganese metal in 1774, which he did by reducing the dioxide with carbon.

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