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Her on-screen partnership with Kevin Cheng was well received by the audience in the years 2004-2008, along with rumours of the two dating in real life (until 2008).
Her other series include The King of Snooker in 2009, with Adam Cheng and Patrick Tang.
As well, in November 2010, she released her last EP under BMA Records: F.
She filmed Sakura Memories (櫻紅醉), a travel documentary programme on Japan, in the spring of 2009 which aired on TVB in August 2009.
Niki signed with BMA Records in 2005 and released her debut EP Pure Niki in the August of that year. She is also the author of several books, including Girlfriend Diary (周麗淇·女朋友手記; 2005), a book of the same title as her 2006 album The Child Woman (2006), Detailed Little Things (細味心事; 2007), Happiness (幸福; 2009), and Cherish (珍惜; 2010).
She is well known for her role and performance in Producer Lau Ka Ho's 2005 series The Gentle Crackdown, which stars Moses Chan and her.
She won the Most Improved Actress award at the TVB Anniversary Awards (2005) for her performance in The Gentle Crackdown.